(Acetylacetonato-κ2 O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ2 N 1,C 1}iridium(III)
نویسندگان
چکیده
In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluoro-phen-yl)pyrazin-2-yl]phenyl ligands and one O,O'-bidentate acetyl-acetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)°.
منابع مشابه
(Acetylacetonato-κ2 O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN 1)phenyl-κC 1]iridium(III)
In the title complex, [Ir(C(17)H(13)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 2-(5-methyl-3-phenyl-pyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetyl-acetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56 (14) and 58.99 (14)° for one mdpp ligand and 9.34 (14) and 79.9...
متن کامل(Acetylacetonato-κ2 O,O′)bis[2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ2 C 1,N]iridium(III)
In the crystal structure of the title compound, [Ir(C(17)H(10)NO)(2)(C(5)H(7)O(2))], the Ir(III) atom is O,O'-chelated by the acetyl-acetonate group and C,N-chelated by the 2-aryl-naphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octa-hedral geometry.
متن کامل(Acetylacetonato-κ2 O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ2 C 1,N]iridium(III)
In the title compound, [Ir(C(18)H(12)NO(2))(2)(C(5)H(7)O(2))], the Ir atom is O,O'-chelated by the acetyl-acetonate group and C,N-chelated by the 2-aryl-naphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octa-hedral geometry. Intra-molecular C-H⋯O hydrogen bonds occur. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into columns parallel to ...
متن کاملAqua[N-(1-naphthyl)acetamido-κN]bis[2-(2-pyridyl)phenyl-κ2 N,C 1]iridium(III) ethylene glycol hemisolvate
In the title compound, [Ir(C(11)H(8)N)(2)(C(12)H(10)NO)(H(2)O)]·0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyrid-yl)phenyl (ppy) ligands, one N atom from the N-(1-naphth-yl)acetamide ligand and one water O atom, forming a distorted octa-hedral environment. Mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds formed by the coordinated...
متن کاملChlorido(pyridine-κN)bis[2-(quinolin-2-yl)phenyl-κ2 C 1,N]iridium(III) monohydrate
In the neutral mononuclear iridium(III) title complex, [Ir(C(15)H(10)N)(2)Cl(C(5)H(5)N)]·H(2)O, the Ir atom is coordinated by two N atoms and two C atoms from two 2-(quinolin-2-yl)-phenyl ligands, one N atom from a pyridine ligand and one Cl atom in an octa-hedral geometry.
متن کامل